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Activated carbons prepared from thermally and chemically treated petroleum and coal tar pitches

机译:由热处理和化学处理的石油和煤焦油沥青制得的活性炭

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摘要

Petroleum and coal tar pitches have been treated thermally at 400°C and 470°C, extracted with toluene and subsequently activated with CO at 900°C. With one exception, the development of the micropore widths and volumes in the resulting carbons follows the trend observed for carbons based essentially on precursors of vegetable origin. On the other hand, petroleum pitch treated at 400°C leads to an active carbon which follows the pattern observed for cokes, semi-cokes and pyrolyzed tyres. It is suggested that the difference between the two types of active carbons is due to the large amount of compounds with low molecular weight left in the petroleum pitch after thermal soaking.
机译:石油和煤焦油沥青已在400°C和470°C进行了热处理,用甲苯萃取,然后在900°C用CO活化。除了一个例外,所得碳中微孔宽度和体积的发展遵循了基本上基于植物来源的前体所观察到的碳趋势。另一方面,在400℃下处理的石油沥青产生活性炭,该活性炭遵循焦炭,半焦炭和热解轮胎所观察到的模式。建议两种活性炭之间的差异是由于在热浸后石油沥青中残留了大量的低分子量化合物。

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